Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 17, Pages 3572-3575Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b909171h
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Funding
- Australian government
- Herchel Smith Harvard Summer Undergraduate Research Fellowship
- Royal Society
- University of New South Wales Faculty Research
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The effect on the rate of reaction of each of a series of Menschutkin processes on changing from a molecular solvent to an ionic liquid was investigated. In each case, the rate acceleration observed at room temperature could be attributed to the change in the entropy of the system on reaching the transition state, offsetting any enthalpic cost.
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