4.6 Article

Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 23, Pages 4817-4820

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b913344e

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Funding

  1. MEXT, Japan [20675002, 21906]

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A cationic rhodium(I)/bisphosphine complex catalyzes carboxylative cyclizations of 1,6-diynes, leading to cyclic dienyl carboxylates, in high yields with high chemo-, regio-, and stereoselectivities under mild reaction conditions.

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