Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 8, Pages 1652-1657Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b819137a
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Funding
- DST [SR/S5/GC-02/2006]
- CSIR, New Delhi
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A simple and efficient procedure for the synthesis of aryl- and vinyl-selenides has been developed by a copper nanoparticle catalysed reaction of aryl iodide/vinyl bromide with diphenyl diselenide in the presence of zinc in water. (E)-Vinyl bromides produce (E)-vinyl selenides stereoselectively, whereas (Z)-vinyl bromides provide mixtures of (E) and (Z) isomers. The catalyst was recycled.
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