Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 7, Pages 1258-1271Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b819255n
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Phospholes are known to exhibit characteristic optical and electrochemical properties derived from the phosphorus-bridged 1,3-dienic pi system. Particular interest has recently been paid to their pi-conjugated derivatives, such as non-fused phospholes, dibenzo[b,d] phospholes, benzo[b] phospholes, benzo[c] phospholes and related compounds. This perspective focuses on recent advances in the synthesis of these phosphole-based pi systems with representative examples that would give valuable guidelines for designing phosphole-containing opto-electrochemical materials.
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