Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 6, Issue 10, Pages 1731-1733Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b803888k
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The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation - fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti S(E)2' mechanism for the fluorination step.
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