Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 6, Issue 20, Pages 3673-3680Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b811162f
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19750029]
- The Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [19750029] Funding Source: KAKEN
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The Stevens rearrangement of N-allylic alpha-aryl amino acid-derived ammonium salts and the Sommelet-Hauser rearrangement of N-benzylic alpha-alkyl amino acid-derived ammonium salts are shown to proceed with remarkably high levels of diastereoselectivity. The methods presented in this work provide new routes to optically active alpha-quaternary alpha-aryl amino acid derivatives.
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