4.6 Article

Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis-Hillman reactions

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 6, Issue 17, Pages 3041-3043

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b808502a

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Funding

  1. Robert A. Welch Foundation [T-1460]

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Three novel chiral ionic liquids (CILs) containing two chiral centers in the side chain bonded to the 2-position of the imidazolium cation and different anions have been synthesized, characterized and used as chiral solvents for asymmetric Baylis-Hillman (BR) reactions; good yields and fair enantioselectivities were obtained.

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