Study on photoluminescence from tris-(8-hydroxyquinoline)indium thin films and influence of light

Tris-(8-hydroxyquinoline)indium (Inq(3)) thin films, one of the metal chelates used in organic electroluminescent (EL) devices, were deposited by thermal evaporation process on glass substrates and were exposed to light for various time periods under the normal ambient. The influence of light exposure on the optical properties of Inq(3) thin films were studied by UV-visible absorption, photoluminescence and time-resolved photoluminescence (TRPL) spectroscopic studies. From the photoluminescence decay analysis of as-prepared Inq(3) thin films, it is found that the photoluminescence originates from two species having different lifetimes (shorter and longer) corresponding to its two geometrical isomers, namely facial and meridional respectively. The photoluminescence lifetimes are decreasing for increasing light exposure time clue to the formation of luminescent quencher during the light exposure. It is reported that the energy of excitons in the light exposed Inq(3) thin films can be non-radiatively transferred to its neighbouring luminescent quencher, quenching the photoluminescence of light exposed Inq(3) thin films. (C) 2011 Elsevier GmbH. All rights reserved.