4.6 Article

Multifunctional photoreactive inorganic cages for three-dimensional holographic data storage

Journal

OPTICS LETTERS
Volume 34, Issue 20, Pages 3095-3097

Publisher

OPTICAL SOC AMER
DOI: 10.1364/OL.34.003095

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Funding

  1. Ministry of Education, Science, and Technology (MEST), Korea [09K1501-02510]
  2. National Research Foundation of Korea [15-2008-00-031-00, 과C6A1907] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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We demonstrate a holographic photopolymer based on multifunctional photoreactive inorganic cages, polyhedral oligomeric silsesquioxane (POSS). It is shown that a second photopolymerizable monomer, POSS, for the photopolymer, contributes to significantly enhance photosensitivity as well as refractive index modulation (Delta n). We also found that during the formation of holographic gratings, polymerization of POSS could effectively suppress volume shrinkage of photopolymer resin, owing to its filler-strengthening effect of inorganic cages accompanied with interpenetrating effect. (C) 2009 Optical Society of America

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