4.6 Article

Enhancement of phosphor efficiency via composition modification

Journal

OPTICS LETTERS
Volume 33, Issue 16, Pages 1816-1818

Publisher

OPTICAL SOC AMER
DOI: 10.1364/OL.33.001816

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Funding

  1. U.S. Department of Energy
  2. Office of Basic Energy Sciences
  3. Division of Chemical Sciences, Geosciences, and Biosciences [DE-AC02-06CH11357]

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The luminescence efficiency of Mn4+-doped CaAl12O19 (Mn:CAO) is significantly improved by composition modification. The leading mechanism that quenches the Mn4+ photoluminescence is the formation of Mn4+ pairs in the lattice of CaAl12O19 (CAO) with interstitial O2- for charge compensation. Mixing Mg2+ ions into the CAO lattice may form Mn4+-Mg2+ pairs and reduce the number of Mn4+ pairs, thus enhancing the Mn4+ luminescence efficiency by more than three times. It is shown that the presence of Mg2+ leads to formation of additional phases that also affect the optical properties of Mn4+. (C) 2008 Optical Society of America.

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