Journal
OPTICS EXPRESS
Volume 20, Issue 4, Pages 4360-4368Publisher
OPTICAL SOC AMER
DOI: 10.1364/OE.20.004360
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Funding
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology (MEST) [2009-0078682]
- Industrial Strategic technology development program [10037416]
- Ministry of Knowledge Economy (MKE, Korea)
- Jiangsu Higher Education Institutions
- Korea Evaluation Institute of Industrial Technology (KEIT) [M002400005] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The self-activated yellow-emitting phosphors of vanadates Ca5M4(VO4)(6) (M = Mg, Zn) were synthesized via the solid-state reaction route. The formation of single phase compound with garnet structure was verified through X-ray diffraction (XRD) studies. The excitation and emission spectra and the thermal quenching of luminescence intensities were measured. The different luminescence properties of Ca5Mg4(VO4)(6) and Ca5Zn4(VO4)(6) phosphors were presented, e. g., the spectra shift, the luminescence lifetimes, the absolute quantum efficiency, the color coordinates and the Stokes shift. This deference was discussed on the base of the relationship between the micro-structure and the charge transfer transitions in [VO4](3-) groups in the lattices. Ca5Mg4(VO4)(6) could be suggested to be a potential yellow-emitting phosphor for the application on near-UV excited white LEDs. (C)2012 Optical Society of America
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