4.6 Article

Laser fabrication of Au nanorod aggregates microstructures assisted by two-photon polymerization

Journal

OPTICS EXPRESS
Volume 19, Issue 23, Pages 22786-22796

Publisher

OPTICAL SOC AMER
DOI: 10.1364/OE.19.022786

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Funding

  1. Iketani Science and Technology Foundation
  2. MEXT, Japan [21686010, 19810012]
  3. National Natural Science Foundation of China [50973126, 61077028]
  4. 973 Project [2010CB934103]
  5. ICP of MOST [2008DFA02050, S2010GR0980]
  6. Grants-in-Aid for Scientific Research [19810012, 21686010] Funding Source: KAKEN

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We demonstrate fabrication of Au nanorod aggregates microstructures by means of a femtosecond near-infrared laser. The laser light was tightly focused into colloidal Au nanorods dispersed in photopolymerizable metyl-methacrylate (MMA) compound to induce two-photon polymerization (TPP). TPP of MMA glued the nanorods together to form solid microstrucures of aggregates. The laser light excited a local surface plasmon, resulting in confinement of TPP in the vicinity of nanorods. Concurrenly occurring optical accumulation of nanorods created a unique mechanism for the formation of nanorod aggregates into desired microstructures. This technique would be a clue for a novel micro/nanofabrication method for plasmonic materials and devices. (C) 2011 Optical Society of America

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