Journal
OPTICS EXPRESS
Volume 18, Issue 13, Pages 13842-13850Publisher
OPTICAL SOC AMER
DOI: 10.1364/OE.18.013842
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Funding
- Spanish Government [MAT2008-05921, MAT2009-14282-C02-02]
- Consolider [CSD2007-00013]
- Basque Country Government [IT-331-07]
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In this work we report the study of energy transfer between Nd3+ and Yb3+ ions in glasses with the 0.8CaSiO(3)-0.2Ca(3)(PO4)(2) eutectic composition at room temperature by using steady-state and time-resolved laser spectroscopy. The Nd3+-> Yb3+ transfer efficiency obtained from the Nd3+ lifetimes in the single doped and codoped samples reaches 73% for the highest Nd3+ concentration. The donor decay curves obtained under pulsed excitation have been used to establish the multipolar nature of the Nd3+-> Yb3+ transfer process and the energy transfer microparameter. The nonradiative energy transfer is consistent with an electric dipole-dipole interaction mechanism assisted by energy migration among donors. Back transfer from Yb3+ to Nd3+ is also observed. (C) 2010 Optical Society of America
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