Journal
THEORETICAL AND EXPERIMENTAL CHEMISTRY
Volume 51, Issue 2, Pages 122-126Publisher
SPRINGER
DOI: 10.1007/s11237-015-9406-x
Keywords
selective catalytic reduction of NO; propane; octane; Ag/Al2O3/cordierite; silver content
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Funding
- National Academy of Sciences of Ukraine [0114U000942]
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An extremal dependence of the catalytic activity of Ag/Al2O3/cordierite on the silver content in the selective catalytic reduction of NO with propane and octane was discovered. The optimum content of Ag was higher during reduction with octane (0.5 wt.%) than with propane (0.3 wt.%). The role of the silver involves formation not only of oxidation-reduction centers but also of additional Lewis acid centers at which activation of the reagents (NO and C (n) H (m) ) occurs.
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