4.7 Article

Synthesis of Mg(OH)2, MgO, and Mg nanoparticles using laser ablation of magnesium in water and solvents

Journal

OPTICS AND LASERS IN ENGINEERING
Volume 46, Issue 11, Pages 829-834

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.optlaseng.2008.05.018

Keywords

laser ablation in liquid; magnesium; magnesium oxides

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Laser ablation of magnesium in deionized water (DW), solutions of DW and sodium dodecyl sulfate (SDS) with different concentrations, acetone and 2-propanol has been conducted. The results showed that ablation in acetone and 2-propanol yielded MgO and Mg nanocrystallites as isolated particles and agglomerated chains probably intermixed with organic residues resulting from the alteration/decomposition of the solvents under the high-energy conditions. Brucite-like Mg(OH)2 particles were mainly produced by laser ablation of Mg in either DW or DW-SDS solutions. Ablation in DW yielded particles of fiber-like shapes having a diameter of about 5-10nm and length-as long as 150 nm. Materials produced in DW-SDS solutions were composed of various size and shape particles. Some had rough surfaces with irregular shapes. Small particles were about 20-30 nm and larger particles were about 120 nm. Particles with rod-like, triangular, and plate-like shapes were also observed. Published by Elsevier Ltd.

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