Journal
OPTICAL MATERIALS
Volume 36, Issue 2, Pages 169-172Publisher
ELSEVIER
DOI: 10.1016/j.optmat.2013.08.021
Keywords
Zinc oxide; Quantum dot; Poly(methyl methacrylate); Nanocomposite; Ultraviolet-shielding
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Funding
- National Natural Science Foundation of China [11104240]
- Jiangsu Government Scholarship for Oversea Studies
- Innovation Project [CXZZ12_0892, 2012JSSPITP1346, 2012JSSPITP1352]
- Natural Science Foundation of Jiangsu Province [11KJB150020]
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We fabricated successfully the visible light (VL)-traversing and ultraviolet (UV)-shielding zinc oxide quantum dots (ZnO QDs)-poly(methyl methacrylate) (PMMA) nanocomposite films by incorporating suitable UV-absorbing ZnO QDs into a transparent PMMA matrix. The ZnO QDs of about 5 nm were first synthesized via a sol-gel route. Then the 3-(trimethoxysilyl)propylmethacrylate (TPM) as a coupling agent is bound to the surface of ZnO QDs, inhibiting the agglomeration of QDs and promoting the compatibility between ZnO QDs and PMMA matrix. Such the transparent ZnO@PMMA nanocomposite films exhibit the prominent UV-absorbing capability and the high optical transparency in the visible-wavelength region, thus have direct practical applications such as UV-shielding windows and glasses. (C) 2013 Elsevier B.V. All rights reserved.
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