Journal
TETRAHEDRON LETTERS
Volume 56, Issue 41, Pages 5661-5664Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.08.068
Keywords
Difluoroalkylation; Photocatalysis; Radical reaction; 1,2-Carbon migration
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Funding
- Soonchunhyang University Research Fund
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2014006224]
- National Research Foundation of Korea [2014R1A2A2A01006224] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A visible-light-mediated photocatalytic ethoxycarbonyldifluoromethylation/1,2-carbon migration of alkenols is described. This approach provides a mild and operationally simple access to the synthesis of difluoralkyl-substituted cyclic ketones via difluoralkylation and 1,2-carbon migration of 1-(1-arylvinyl) cyclobutanol derivatives. (C) 2015 Published by Elsevier Ltd.
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