Journal
TETRAHEDRON LETTERS
Volume 56, Issue 12, Pages 1520-1523Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.02.022
Keywords
Electrochemistry; Fluoroarenes; Hydrodefluorination; Borohydride
Categories
Funding
- National Natural Science Foundation of China [21172080, 21372089]
- Changjiang Scholars and Innovation Team Project of Ministry of Education
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The BH4-- promoted electrochemical hydrodefluorination of fluoroaromatic compounds was reported. Using platinum as electrodes in an undivided cell, the electrolysis was carried out at constant current at room temperature under air without the need of pretreatment of the solvent. This reaction could proceed smoothly on both nonactivated monofluoroarenes and perfluoroarenes with high yields and good selectivities. (C) 2015 Elsevier Ltd. All rights reserved.
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