Journal
TETRAHEDRON LETTERS
Volume 56, Issue 40, Pages 5460-5464Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.08.017
Keywords
Alkaloid; Asymmetric; Cyclization; Natural product; Synthesis
Categories
Funding
- National Natural Science Foundation of China [21272242]
- Yunnan High-End Technology Professionals Introduction Program [2010CI117]
- National Basic Research Program of China [2011CB915500]
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The asymmetric synthesis of common aza-tricyclic core of different types of natural alkaloids had been accomplished from commercially available L-Cbz-tyrosine. This practical approach was capable of generating scale-up aza-tricyclic skeleton. Meanwhile, it will facilitate the manipulating functionalities on the aza-tricyclic framework further, for the purpose of target-oriented synthesis of a large number of different natural alkaloids containing this versatile aza-tricyclic structure. (C) 2015 Elsevier Ltd. All rights reserved.
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