Journal
TETRAHEDRON LETTERS
Volume 56, Issue 15, Pages 1991-1993Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.02.115
Keywords
Photoswitches; Molecular devices; Energy transfer; Photochemistry; Photophysics
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Funding
- Spanish Ministerio de Ciencia e Innovacion (MICINN)/Fondos Europeos para el Desarrollo Regional (FEDER) [CTQ2011-24800]
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Neutral rhodopsin-based molecular photoswitches can be activated by using low-energy visible light through sensitized irradiation. The triplet state of the neutral and protonated forms are studied and compared by the use of different experimental conditions, laser flash photolysis, and theoretical calculations. The use of common, visible light absorbing sensitizers allows for the photoisomerization without the requirement of acidic water solutions. (C) 2015 Elsevier Ltd. All rights reserved.
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