Journal
TETRAHEDRON
Volume 71, Issue 23, Pages 3857-3862Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.04.021
Keywords
Cyclen; Bisaminal; Deprotection; Cyclen-glyoxal; 1,4,7,10-Tetraazacyclododecane
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Funding
- Ministere de l'Enseignement Superieur et de la Recherche
- CNRS
- ANR program BiBiChemAp
- 'Ligue versus Cancer' foundation
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Strategic removal of the bisaminal bridge of N-mono- and N-1,N-7-difunctionalised cyclen glyoxal derivatives was carried out via transamination processes with vicinal diamines. These procedures were found to be particularly well-suited for cyclen targets bearing sensitive groups. (C) 2015 Elsevier Ltd. All rights reserved.
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