Journal
TETRAHEDRON
Volume 71, Issue 12, Pages 1792-1798Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.02.005
Keywords
DNA nucleobases; 9-(2-Bromoethyl)adenine; Adenine derivatives; Chalcogens; Woollins' reagent
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Funding
- University of St Andrews
- EPSRC [EP/K031252/1, EP/K039210/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039210/1, EP/K503940/1, EP/K031252/1] Funding Source: researchfish
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The formation of a library of chalcogen-containing DNA nucleobase derivatives is presented. Reacting easily accessible 9-(2-bromoethyl)adenine with chalcogen-containing nucleophilic reagents led to a series of novel heteroatom derivatives incorporating S, Se and Te atoms in satisfactory yields. Two representative X-ray structures are reported. (C) 2015 Elsevier Ltd. All rights reserved.
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