Journal
TETRAHEDRON
Volume 71, Issue 36, Pages 6285-6289Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.06.038
Keywords
Cyanoborate; Rearrangement; Hydroboration; Imidoyl chloride
Categories
Funding
- Engineering and Physical Sciences Research Council
- Cardiff University
- King Saud University [RGP-VPP-239]
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Methods for generating tert-alkyl organoboron species are in high demand as they are invaluable intermediates for the synthesis of quaternary carbon centres. Herein we report investigations into generation of tert-alkyl organoboron species using imidoyl chlorides as reagents in the organoboron cyanidation reaction. Although alkenyl side-products predominate in particularly hindered cases, tert-alkyl organoboron species can be successfully generated for less hindered examples. (C) 2015 Elsevier Ltd. All rights reserved.
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