Journal
SYNTHESIS-STUTTGART
Volume 47, Issue 23, Pages 3645-3668Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1560646
Keywords
arylsilanes; transition metal; silylation; homogeneous catalysis; cross-coupling
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Funding
- National Natural Science Foundation of China [21173064, 21472031]
- Zhejiang Provincial Natural Science Foundation of China [LR14B030001]
- Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT) [JTAS 2011-01-014, JTAS 2011-01-017]
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Arylsilanes are valuable organosilicon compounds and attract significant research interest due to their promising applications in organic synthesis. The development of aromatic C-Si cross-coupling reactions represents a major challenge in both organosilicon chemistry and organic synthesis. A number of investigations are focused on developing transition-metal-catalyzed Si-C coupling reactions due to the associated high atom economy and superior functional group compatibility. This review describes recent advances in transition-metal-catalyzed selective silylations of aryl C-H and C-X (X = halide) bonds with hydrosilanes. 1 Introduction 2 Silylation of Arenes with Hydrosilanes via Aryl C-H Bond Activation 2.1 Rhodium-Catalyzed Dehydrogenative Silylations 2.2 Iridium-Catalyzed Dehydrogenative Silylations 2.3 Ruthenium-Catalyzed Dehydrogenative Silylations 2.4 Platinum-Catalyzed Dehydrogenative Silylations 2.5 Other Transition-Metal-Catalyzed Dehydrogenative Silylations 3 Silylation of Arenes with Hydrosilanes via Aryl C-X Bond Cleavage 3.1 Palladium-Catalyzed Silylations of Aryl Halides 3.2 Rhodium-Catalyzed Silylations of Aryl Halides 3.3 Platinum-Catalyzed Silylations of Aryl Halides 4 Conclusion
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