Journal
SYNTHESIS-STUTTGART
Volume 47, Issue 16, Pages 2439-2445Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378715
Keywords
multicomponent reaction; halotrifluoromethylation; photoredox catalysis; halogen; Umemoto's reagent
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Funding
- ICSN
- CNRS
- Labex Charmmmat
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A mild and simple three-component procedure for the direct vicinal halotrifluoromethylation of styrenes and aliphatic alkenes has been developed in the presence of [Ru(bpy)(3)](PF6)(2) as a photosensitizer and Umemoto's reagent as the CF3 source. The multicomponent method offers the advantage of short reaction time, moderate to good yields, and mild reaction conditions.
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