Journal
SYNTHESIS-STUTTGART
Volume 47, Issue 22, Pages 3460-3466Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378810
Keywords
phenanthridines; trifluoromethylation; Langlois reagent-cyclization
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Funding
- National Natural Science Foundation of China [21272177]
- Zhejiang Provincial Natural Science Foundation of China [LR15B020002]
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A mild and efficient procedure for the silver-catalyzed tandem trifluoromethylation and cyclization of aryl isonitriles with the Langlois reagent (sodium triflinate) is developed. A series of trifluoro-methylated phenanthridines is prepared in moderate to good yields from a cheap and stable trifluoromethyl source.
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