Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 5, Pages 730-736Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561280
Keywords
bismuthanes; diselenides; selenides; copper; catalysis; cross-coupling
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Funding
- Institute of Pharmaceutical Life Sciences, Aichi Gakuin University
- Hokuriku University
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Copper-catalyzed C(aryl)-Se bond formation by the reaction of diaryl diselenides with triarylbismuthanes in the presence of copper(I) acetate (10 mol%) and 1,10-phenanthroline (10 mol%) under aerobic conditions led to the formation of unsymmetric diaryl selenides in moderate to excellent yields. This reaction proceeded efficiently; all three aryl groups in the bismuthane and both the selanyl groups in the diaryl diselenide were transferred to the coupling products.
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