Journal
SYNTHESIS-STUTTGART
Volume 47, Issue 19, Pages 2931-2936Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1380418
Keywords
C-C bond activation; allylic amination; homoallylic alcohols; palladium; allylic amines
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Funding
- National Natural Science Foundation of China [21302183]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09030102]
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An efficient approach for palladium(II) acetate catalyzed allylic amination of homoallylic alcohols with various amines via sequential retro-allylation and amination was developed, which afforded the corresponding allylic amines in up to 98% yield.
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