Journal
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
Volume 46, Issue 8, Pages 1202-1206Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2015.1004441
Keywords
Cd(II) compound; luminescence; terephthalic acid; hexanuclear cluster
Funding
- Sci-technical Support Project of Baoding City Technology Bureau [14ZF025]
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A new Cd(II) coordination polymer, namely {Cd-3(pbdc)(3)(e-murea)(DMF)}(n center dot)n(e-murea) (1, H(2)pbdc = terephthalic acid, e-murea = 1,3-dimethyl-2-imidazolidinone, DMF = N,N'-dimethylformamide), has been successfully synthesized via the urothermal reactions of Cd(II) ions and terephthalic acid ligand. Single-crystal X-ray structural analysis reveals that 1 features a two-dimensional layer framework with rod-shaped hexanuclear {Cd-6(COO)(12)} clusters as building subunits. In addition, the luminescent property of 1 was also studied at room temperature.
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