4.4 Article

Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry

Journal

SYNLETT
Volume 27, Issue 5, Pages 714-723

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561297

Keywords

cyclic voltammetry; photoredox catalysis; redox potential; electron transfer; computational chemistry

Funding

  1. NSF-CAREER grant [CHE-1352490]
  2. NSF
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1352490] Funding Source: National Science Foundation

Ask authors/readers for more resources

Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available