Journal
SYNLETT
Volume 26, Issue 10, Pages 1413-1416Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1380680
Keywords
asymmetric synthesis; BrOnsted acid catalysis; electrophilic amination; alpha-branched ketones; enol catalysis; azodicarboxylates
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Funding
- Max Planck Society
- Fonds der Chemischen Industrie
- GC department of the MPI fur Kohlenforschung
- HPLC department of the MPI fur Kohlenforschung
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We report a highly enantioselective -amination of -branched ketones catalyzed by a chiral phosphoric acid employing azodicarboxylates as reagents. The desired products were obtained in good to excellent yields and enantioselectivities.
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