Journal
SYNLETT
Volume 26, Issue 11, Pages 1515-1519Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1380424
Keywords
homocoupling; manganese; metalation; dimerization; oxidation
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Funding
- CNRS
- Chimie ParisTech (Paris, France)
- Ludwig-Maximilians-University (Munich, Germany)
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We report an oxidative homocoupling of diheteroaryl or diarylmanganese reagents prepared by directed manganation using TMP(2)Mn2MgCl(2)4LiCl. The resulting diorganomanganese reagents can efficiently undergo an oxidative dimerization leading to the homocoupling products in good yields. Remarkably, a number of functional groups, as well as sensitive heterocycles are tolerated using this metalation-dimerization procedure.
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