Journal
NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 20, Pages 16863-16874Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj03065k
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Funding
- Region Auvergne-Rhone-Alpes, France (ARC environment project)
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Two strategies have been explored towards the heterogenization of a host-guest catalytic system where either cavitand host [3iPO] or quaternary ammonium catalysts are grafted on silica supports. The bis-propargyl substituted triphosphonate cavitand [3iPO] was clicked onto an azido functionalized ultra-large pore SBA-15 type silica (UL-SBA-15). Ammonium hybrid materials were produced by grafting a propyltrimethylammonium chloride silane precursor onto silicas of varying porosities and textural properties (UL-SBA-15, SBA-15 and SiO2). Extensive characterization of each material is presented (XRD, N-2 sorption, TGA, solid state NMR, elemental analyses, FT-IR). The effect of heterogenization was investigated in the coupling of CO2 with styrene oxide and was compared to all-soluble cavitand/ammonium homogeneous analogs.
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