Journal
NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 21, Pages 17513-17523Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj03805h
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Funding
- Foundation for Science and Technology (FCT), Portugal [UID/QUI/00100/2013]
- FCT [SFRH/BPD/76192/2011, SFRH/BPD/78264/2011]
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Reactions of 3-amino-2-pyrazinecarboxylic acid (HL) with SnCl2 under different hydrothermal conditions and crystallization processes produced two new mononuclear Sn(ii) compounds (1 and 2) of general formula [Sn(N,O-L)(2)] (L = 3-amino-2-pyrazinecarboxylate), and single crystal X-ray diffraction analysis indicated that they are packing polymorphs, complex 1 crystallizing in the monoclinic C2/c space group whereas 2 in the monoclinic P2(1)/c. The Hirshfeld surface analysis shows that the supramolecular features of both forms are guided by SnO and SnN contacts, as well as by strong N-HO and N-HN hydrogen bonds that differentiate the packing in the two forms. Complex 1 shows a one dimensional hydrogen bonded network whereas 2 shows a 2D hydrogen bonded network. To the best of our knowledge no examples of packing polymorphs based on tin(ii) complexes have been reported so far. These polymorphs are interconvertible when immersed in a suitable solvent or mixture of solvents. They also act as heterogeneous catalysts for the cyanosilylation reaction of aldehydes with trimethylsilyl cyanide (TMSCN) and can be recycled several times without losing activity.
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