4.6 Article

Selective recognition of solvent molecules in solution and the solid state by 1,4-dimethoxypillar[5]arene driven by attractive forces

Journal

NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 2, Pages 845-851

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nj01498c

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Funding

  1. National Natural Science Foundation of China [21272093]
  2. Research Fund for the Doctoral Program of Higher Education of China [20120061120117]
  3. Innovation Program of the State Key Laboratory of Supramolecular Structure and Materials

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Highly selective binding of solvent molecules by 1,4-dimethoxypillar[5]arene (DMP[5]A) and their host-guest complexation in solution and the solid state have been investigated by multiple methods. Enthalpy changes and the size-fit effect play an important role in the high selectivity.

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