4.6 Article

High-yield synthesis of poly(m-phenylenediamine) hollow nanostructures by a diethanolamine-assisted method and their enhanced ability for Ag+ adsorption

Journal

NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 8, Pages 3984-3991

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj00323c

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Funding

  1. program for Changjiang Scholars
  2. National Funds for Distinguished Young Scientists of China [2011AA0610011]
  3. National Natural Science Foundation of China [51374237]
  4. Award for Excellent Doctoral Student - Ministry of Education, China [113501027]
  5. Shanghai Tongji Gao Ting-Yao Environmental Science and Technology Development Foundation

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A diethanolamine-assisted (DEA-assisted) conventional oxidation method was explored to synthesize the hollow nanostructures of poly(m-phenylenediamine) (PmPD) with a high specific surface area. The DEA concentration has a significant influence on the PmPD morphology and a possible formation mechanism has been proposed. The obtained hollow nanostructures show an excellent Ag+ adsorption ability with an adsorbance of 2359.3 mg g(-1), much higher than other reported materials.

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