Journal
NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 4, Pages 1780-1788Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nj01598j
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Funding
- National Natural Science Foundation of China [20872121]
- CQ CSTC [2013jcyjA50026]
- Research Funds for the Doctoral Program of Higher Education of China [20090182120010]
- Southwest University Doctoral Fund [SWUB2008075]
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Photoresponsive surface molecular imprinting polymer (SMIP) microspheres were synthesized on silica microspheres by surface polymerization using a water-soluble azobenzene-containing 4-[(4-methacryloyloxy)phenylazo]benzenesulfonic acid as the functional monomer. The SMIP microspheres displayed good photo-responsive properties and specific affinity towards bisphenol A (BPA) with high recognition ability (maximal adsorption capacity: 6.96 mu mol g (1)) and fast binding kinetics (binding constant: 2.47 x 10(4) M (1)) in aqueous media. Upon alternate irradiation at 365 and 440 nm, the SMIP microspheres could quantitatively bind and release BPA. Analytical application of the SMIP microspheres for the detection of trace BPA concentration in mineral water and tap water has been carried out successfully, and therefore a simple and quick detection method for trace BPA in the environment was established.
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