Journal
NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 2, Pages 499-502Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nj01416a
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Funding
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canadian Foundation for Innovation (CFI)
- Ontario Research Fund
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Reaction of IMes=PPh with RuCl2L2(CHPh) (L = PPh3 and PCy3) gave complexes with selectivity that is dependent on the metal precursor used. RuCl2(IMes=PPh)(PPh3)(CHPh), which adopts the rare cis chloride configuration, was inactive in ring-opening metathesis of diallyl sulfide. In contrast, the PCy3 analogue could not be isolated, and in fact led to an unusual decomposition product with two C-H activations.
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