4.6 Article

Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes

Journal

NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 9, Pages 4032-4035

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj00739e

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Funding

  1. National Natural Science Foundation of China [21201134]
  2. Natural Science Foundation of Jiangsu Province [BK20130370]
  3. Natural Science Foundation of Hubei Province [2013CFB288]
  4. Ministry of Science and Technology of China [2011YQ12003504]
  5. Large-scale Instrument and Equipment Sharing Foundation of Wuhan University

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Ultrafine Ru nanoparticles were successfully immobilized inside the pores of MIL-101 by using a simple liquid impregnation method. The turnover frequency (TOF) value of the as-synthesized 2.80 wt% Ru@MIL-101 toward catalytic hydrolysis of ammonia borane is 178 mol H-2 min(-1) (mol Ru)(-1), which is among the highest values ever reported.

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