4.6 Article

A low-κ dielectric metal-organic-framework compound showing novel three-step dielectric relaxations originating from orientational motion of dipolar guest molecules

Journal

NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 6, Pages 2254-2257

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nj01551c

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Funding

  1. Priority Academic Program Development of Jiangsu Higher Education Institutions
  2. National Nature Science Foundation of China [91122011, 21271103, 21176115]

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A three-dimensional metal organic framework compound with a formula [Cu-2(EBTC)(H2O)(2)center dot 8H(2)O center dot DMF center dot DMSO](infinity) (EBTC = 1,1'-ethynebenzene-3,3',5,5'-tetracarboxylate) shows novel three-step dielectric relaxations arising from the orientational motion of dipolar guest molecules and its guest-free framework displays low-x dielectric permittivity.

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