4.6 Article

Facile fabrication and enhanced gas sensing properties of In2O3 nanoparticles

Journal

NEW JOURNAL OF CHEMISTRY
Volume 38, Issue 10, Pages 4879-4884

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj00901k

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Funding

  1. National Science Foundation of China [11174103, 90923032]
  2. Specialized Research Fund for the Doctoral Program of Higher Education of China [20130061110012]

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Nanoscale single crystalline In2O3 nanoparticles with sizes of 10-40 nm are prepared by annealing gas-liquid phase chemical deposition-synthesized In2S3 nanoparticles and are developed for the detection of acetone gas. The In2O3 nanoparticles are characterized by TEM, HRTEM, SAED, EDX and XRD. Moreover, the products are further studied by room temperature UV-absorption and photoluminescence (PL) spectroscopy. To demonstrate the usage of such nanoparticles, gas sensors based on the as-synthesized In2O3 nanoparticles are fabricated and exhibit good selectivity, high sensitivity, rapid response, a low concentration detection limit and better repeatability towards acetone gas at a relatively low operating temperature. Such excellent gas sensing performances are attributed to small crystal sizes and the existence of abundant oxygen vacancies. As demonstrated, the single crystalline In2O3 nanoparticles are highly promising for real-time monitoring gas sensor applications.

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