Journal
NEW JOURNAL OF CHEMISTRY
Volume 37, Issue 6, Pages 1736-1741Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nj00044c
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Funding
- National Natural Science Foundation of China [21072028, 21272036]
- National Basic Research Program of China [2012CB21600]
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An unprecedented copper-mediated oxidative difluoromethylenation of aryl boronic acids with alpha-silyldifluoromethylphosphonates has been developed, allowing rapid access to a wide range of aryldifluorophosphonates containing various functional groups. This method provides a complementary and alternative method to Cu-mediated cross-couplings of aryl iodides with metalated difluoromethylphosphonates.
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