4.6 Article

2-Thiohydantoin containing OH and NH recognition subunits: a fluoride ion selective colorimetric sensor

Journal

NEW JOURNAL OF CHEMISTRY
Volume 37, Issue 5, Pages 1591-1594

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nj41134f

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Funding

  1. National Natural Science Foundation of China [21074073, 51173050, 21244007]

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A novel anion receptor based on 2-thiohydantoin, containing different hydrogen bonding donors such as OH and NH groups, was synthesized. This receptor showed a colorimetric response to fluoride ions. H-1 NMR titration confirmed the deprontonation of the phenol OH group and hydrogen bonding interaction between NH group and F-

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