Journal
NEW JOURNAL OF CHEMISTRY
Volume 36, Issue 9, Pages 1769-1773Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj40255f
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Funding
- MEXT (Ministry of Education, Culture, Sports, Science and Technology) [24105513, 2304]
- Asahi Glass Foundation
- Hori Sciences & Arts Foundation
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A series of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts 1 were readily synthesized by treatment of corresponding (bromodifluoromethyl)arylsulfoxides 2 and substituted benzenes 3 with triflic anhydride in moderate to good yields. The unsymmetrical sulfonium salts 1 with different aryl groups having electron-donating or electron-withdrawing substituents can be nicely constructed depending on the choice of 2 and 3. Bromodifluoromethylation of alkynes was evaluated by using the selected diarylsulfonium salts 1 to provide the desired bromodifluoromethylated alkynes in moderate to good yields.
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