Journal
NEW JOURNAL OF CHEMISTRY
Volume 36, Issue 5, Pages 1149-1152Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj20912h
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC00001055]
- Center for Electrocatalysis, Transport Phenomena, and Materials (CETM) for Innovative Energy Storage, an Energy Frontier Research Center
- Argonne-Northwestern Solar Energy Research (ANSER) Center EFRC [DE-PS02-08ER15944]
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A Ni-II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.
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