Journal
NEW JOURNAL OF CHEMISTRY
Volume 36, Issue 4, Pages 1080-1084Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj20811c
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Funding
- National Natural Science Foundation of China [50803015, 20871041, 30800175]
- Henan University [SBGJ090506]
- Henan Provincial Department of Education [2011B430001]
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Two core-tetrachlorinated perylenediimide derivatives PTCDI-ClC12 and PTCDI-ClC4F7 bearing electron-donor dodecyl and electron-withdrawing fluorobutyl groups at the imide positions, respectively, were prepared. The determination of sensing properties based on their conductometric gas sensors revealed that both devices had the same sensitivity to the hydrazine vapor and approximately 4 orders of magnitude in resistance decreased upon exposure to the hydrazine vapor (10 ppm). Whereas approximately 2 orders of magnitude in resistance decreased for another core-unsubstituted PTCDI-C-12 gas sensor that was also prepared for comparison purpose. The differential response to the hydrazine vapor for the core-tetrachlorinated PTCDI-ClC12 and core-unsubstituted PTCDI-C-12 was independent of their surface area and morphologies and was ascribed to the difference in their reduction potentials that originated from different bay-substituted groups and the twisted skeleton of the PTCDI-ClC12 molecule. The similar LUMO energy levels of PTCDI-ClC12 and PTCDI-ClC4F7 led to both of them possessing similar sensing performance, which in turn indicated that the substituents at the imide positions have little effect on the improvement of performance of perylenediimide derivatives gas sensors.
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