4.6 Article

Pyrene end-capped oligothiophene derivatives for organic thin-film transistors and organic solar cells

Journal

NEW JOURNAL OF CHEMISTRY
Volume 36, Issue 9, Pages 1813-1818

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj40348j

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Funding

  1. Basic Science Research Program through an NRF grant
  2. MEST for the Center for Next Generation Dye-sensitized Solar Cells [2012-0000591]
  3. New & Renewable Energy Technology Development Program of the KETEP grant [20113020010070]
  4. Ministry of Knowledge Economy
  5. BK21 program

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We have demonstrated an efficient one-step synthesis of pyrene end-capped thiophene oligomers as active materials for organic thin-film transistors (OTFTs) and donor materials for organic solar cells (OSCs). In particular, the OTFT device based on 5,5 ''-di(pyren-1-yl)-2,2':5',2 ''-terthiophene (3s) exhibited a reasonable field effect mobility of 0.11 cm(2) V (1) s (1), and a power conversion efficiency of 1.20% was achieved when 3s was used as active materials in OSCs. These pyrene end-capped thiophene oligomers are considered to be good organic semiconducting materials for OTFTs and OSCs.

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