Journal
NEW JOURNAL OF CHEMISTRY
Volume 35, Issue 1, Pages 18-23Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nj00776e
Keywords
-
Categories
Funding
- solar and EFRC [DE-FG02-84ER13297, DE-FG02-07ER15909, DE-PS02-08ER15944, DE-SC-0001055, DE-SC-0001298]
Ask authors/readers for more resources
Sophisticated ligands are now being designed that do far more than just fulfil their traditional spectator roles by binding to the metal and providing a sterically-defined binding pocket for the substrate in homogeneous transition metal catalysis. This Focus review emphasizes selected cases in which ligands carry additional functional groups that change the properties of the ligand as a result of an external stimulus or undergo catalytically-relevant ligand-based reactivity. These include proton responsive ligands capable of gaining or losing one or more protons, ligands having a hydrogen bonding function, electroresponsive ligands capable of gaining or losing one or more electrons, and photoresponsive ligands capable of undergoing a useful change of properties upon irradiation. Molecular recognition ligands and proton coupled electron transfer (PCET) are briefly discussed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available