Journal
NEW JOURNAL OF CHEMISTRY
Volume 35, Issue 3, Pages 546-550Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nj00836b
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Funding
- French National Research Agency (ANR) [ANR-08-PCO2-001-02]
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The zinc benzimidazolate coordination polymer (ZIF-7) shows a reversible gate-opening effect upon variation of partial pressure of CO2 or temperature. This phenomenon, which is unique for a MOF with sodalite topology, arises from a phase-to-phase transformation upon guest adsorption-desorption.
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