Journal
NEW JOURNAL OF CHEMISTRY
Volume 34, Issue 11, Pages 2396-2399Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nj00272k
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Funding
- WCU [R31-2008-000-20012-0]
- UNIST
- [NRF-2009-0052888]
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A two-fold interpenetrated metal-organic framework (MOF), [(Zn4O)(2)L-4(DMF)(2)(H2O)(3)], was prepared using the tritopic ligand 4,4',4 ''-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid (H3L) and zinc nitrate. The MOF, based on the hexatopic tetranuclear Zn4O(COO)(6) secondary building unit, has a (3,6)-connected network with an rtl topology and a large solvent cavity.
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